Abstract
In this work, we report the production of new composite perovskite manganite system CaMn ,Ti,O, with doping x = 0.25, 0.5 and 0.75, reaction sintering method solid state. Structural characterization was performed using the technique of X-ray Diffraction (XRD) and the Rietveld method, obtaining a tetragonal structure, with Prima spatial group (# 62) (a=5.3586a y a=5.2997A: b=7.5041 A y b=7.5526a; c+5.3l82& y c=5.3278A). In this paper takes the discussion on possible structural changes with changes in the system titanium CaMn, ,Ti,O,.
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References
Gil de Muro Izaskun, Insausti Maite, Lezama Luis, Rojo Teñfilo, Mor- phological and magnetic study of CaMnO, , oxides obtained from di- fferent routes, journal of Solid State Chemistry 178 (2005): 925-936.
llelmolt Von, Wecker R., Holzapfel â., Schuftx B., L. and Sa- mwer, K. Giant negative magnetoresistance in perovskita-like La2/3Ba 1/3MnOx ferromagnetic film, Phys. Rev. Nett. Al (1993): 2331-2336.
Kuwahara H. and Tokiira Y., “Colossal Magnetoresistance, Charge Orde- ring and Related Properties of Manganese Oxides”, C.N.R. (1998): 217-216,
Kupriyanov M.F.,k S. Filip’ev, Kristallografiya (1963): 356-370.
Nagaev E. L., Colossal-Ma grretoresistance materials: manganites and conventional ferromagnetic semiconductors, Physics Reports, 346, (2001): 387-392.
Ochoa Burgos R., Martínez B. D., Parra Vargas C. A., Landinez Téllez D. A., Vera López E., Sarmiento Santos A., Roa-Rojas J., Magne- tic and ferroelectric responde of CazTiMnO, manganíte-like perovs- kite Revista Mexicana de Física S 58 (2012): 4W6.
Raveau B., Maignan A., Martic C., Hervieii M., Colossal Magnetorresis- tance manganite perosvkites: Relation between crystal chemistry and propertries. lem. Mater. 10 (1998): 2641-2644.
Raveau B., Zhao Y. M., Martin C., tlervieu M. and Maignan A. Mn-Site Doped CAMnO3: Creation of the CMR Effect Journal of Solid State Chemistiy 149, (2000): 203-207.
Roa-Rojas, Salazar J. Llamosa C., Xeon-Vanegas D., L'andinez, Pe- reur D., Dias, F. T. Vieir, V. N., Magnetoelectric Response of new Sr2TiMnO6 manganite-like material, Journal of Magnetism and Magnetic Materials 320 (2008): 104-106.
Shahle 4.M. S. and A. R. Superconducting La, ,Ba, „ yCa,Cu,O solid solutions I. Phase diagram, cation stoichiometry and T data. West, Physica C, vol. 220, (1994): I87-194.
Valldor Marfin, Esmaeitzadeh Saeid, Anderson Magnus, Morawski Andrzej. Preparation and characterization of the double perovskita SrzTaMnOt. Journal of magnetism and magnetic materials 299 (2006): 16 I-169
Yung R. A., the Rietveld Method, (Oxford University Press. (1993).
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