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- Miller A. Ruidiaz, Daniel R. Delgado, Fleming Martínez, PERFORMANCE OF THE JOUYBAN-ACREEAND YALKOWSKY-ROSEMAN MODELSFOR ESTIMATING THE SOLUBILITY OFINDOMETHACIN IN ETHANOL + WATERMIXTURES , Revista de la Academia Colombiana de Ciencias Exactas, Físicas y Naturales: Vol. 35 No. 136 (2011)
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Abstract
Molar volumes, excess molar volumes, and partial molar volumes were investigated for glycerol formal + ethanol mixtures by density measurements at several temperatures. Excess molar volumes are fitted by the Redlich-Kister equation and compared with other systems. The system exhibits negative excess volumes, probably due to increased H-bond interactions. Volume thermal expansion coefficients are also calculated. The Jouyban-Acree model was used for density and molar volume correlations at different temperatures. The mean relative deviations between experimental and calculated data were 0.03 ± 0.03% and 0.17 ± 0.13%, respectively, for density and molar volume data. Also, using a minimum number of data points, the Jouyban-Acree model can predict density and molar volume with acceptable accuracies (0.03 ± 0.03% and 0.15 ± 0.12%, respectively).
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References
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