Catalytic oxidation of phenol in rice parboiling effluents: a strategy toward a circular economy
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Keywords

Catalyst
oxidation
wastewater
phenol
circular economy

How to Cite

Peralta, Y. M., Molina, R., & Moreno, S. (2026). Catalytic oxidation of phenol in rice parboiling effluents: a strategy toward a circular economy. Revista De La Academia Colombiana De Ciencias Exactas, Físicas Y Naturales. https://doi.org/10.18257/raccefyn.4178

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Abstract

Rice parboiling effluents contain non-biodegradable compounds that are toxic to aquatic ecosystems. Here, we used a highly dispersed Fe catalyst supported on rice husk-derived silica (5Fe@SiO₂) to oxidize phenol in rice parboiling wastewater. The reaction was carried out at 25 °C under atmospheric pressure. The catalyst achieved a 67% reduction in chemical oxygen demand (COD), 68.4% mineralization, and 81.4% phenol conversion after 36 hours. These results demonstrate the catalyst’s potential for application in wastewater treatment, whose implementation represents a valuable strategy for conserving natural resources and preserving biodiversity in Colombia. Our results contribute to the transition toward a circular economy by promoting the valorization of rice husk-derived silica as a sustainable catalyst support.

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References

Adam, F., Andas, J., Rahman, I. A. (2010). A study on the oxidation of phenol by heterogeneous iron silica catalyst. Chemical Engineering Journal, 165(2), 658-667. https://doi.org/10.1016/j.cej.2010.09.054

American Public Health Association - APHA. (2005). Standard Methods for the examination of water and waste-water. American Public Health Association.

Behera, M., Jana, P. S., More, T. T., Ghangrekar, M. M. (2010). Rice mill wastewater treatment in microbial fuel cells fabricated using proton exchange membrane and earthen pot at different pH. Bioelectrochemistry, 79(2), 228-233. https://doi.org/10.1016/j.bioelechem.2010.06.002

Challa, M., Dash, R. R., Behera, M. (2024). A review on treatment of rice mill wastewater with emphasis on biological technologies. International Biodeterioration and Biodegradation (Vol. 195). Elsevier. https://doi.org/10.1016/j.ibiod.2024.105895

DANE. (2026). Encuesta nacional de arroz mecanizado (ENAM). Información primer semestre 2026. https://www.dane.gov.co/

Díaz-Tovar, D., Molina, R., Moreno, S. (2025). Effect of leaching and catalytic decomposition on the kinetics and thermodynamics of rice husk pyrolysis. Biomass and Bioenergy, 193, 107564. https://doi.org/10.1016/j.biombioe.2024.107564

Environmental Protection Agency - EPA. (2016) Phenol. https://nepis.epa.gov/

Food and Agriculture Organization of the United Nations - FAO. (2026). CODEX STAN 198-1995. FAO. https://www.fao.org/

Jaramillo, L. Y., Arango-Benítez, K., Henao, W., Vargas, E., Recio-Sánchez, G., Romero-Sáez, M. (2019). Synthesis of ordered mesoporous silicas from rice husk with tunable textural properties. Materials Letters, 257, 126749. https://doi.org/10.1016/j.matlet.2019.126749

Kandagatla, N., Kunnoth, B., Sridhar, P., Tyagi, V., Rao, P. V., Tyagi, R. D. (2023). Rice mill wastewater management in the era of circular economy. Environmental Management, 348, 119248. https://doi.org/10.1016/j.jenvman.2023.119248

Kumar, A., Priyadarshinee, R., Singha, S., Sengupta, B., Roy, A., Dasgupta, D., Mandal, T. (2019). Biodegradation of alkali lignin by Bacillus flexus RMWW II: Analyzing performance for abatement of rice mill wastewater. Water Science and Technology, 80(9), 1623-1632. https://doi.org/10.2166/wst.2020.005

Kumar, A., Singha, S., Sengupta, B., Dasgupta, D., Datta, S., Mandal, T. (2016). Intensive insight into the enhanced utilization of rice husk ash: Abatement of rice mill wastewater and recovery of silica as a value added product. Ecological Engineering, 91, 270-281. https://doi.org/10.1016/j.ecoleng.2016.02.034

Mazivila, S. J., Ricardo, I. A., Leitão, J. M. M., Esteves da Silva, J. C. G. (2019). A review on advanced oxidation processes: From classical to new perspectives coupled to two- and multi-way calibration strategies to monitor degradation of contaminants in environmental samples. Trends in Environmental Analytical Chemistry, 24, e00072. https://doi.org/10.1016/j.teac.2019.e00072

Mishra, S. K., Bhunia, P., Sarkar, A. (2024). An innovative combination of constructed wetland and vermifiltration system: Treatment of synthetic rice mill effluent in relation to phenol concentration and length of the wetland. Journal of Water Process Engineering, 67, 106256. https://doi.org/10.1016/j.jwpe.2024.106256

Mukherjee, C., Chowdhury, R., Sutradhar, T., Begam, M., Ghosh, S. M., Basak, S. K., Ray, K. (2016). Parboiled rice effluent: A wastewater niche for microalgae and cyanobacteria with growth coupled to comprehensive remediation and phosphorus biofertilization. Algal Research, 19, 225-236. https://doi.org/10.1016/j.algal.2016.09.009

Ni, Z., Qin, H., Kang, S., Bai, J., Wang, Z., Li, Y., Zheng, Z., Li, X. (2018). Effect of graphitic carbon modification on the catalytic performance of Fe@SiO 2 -GC catalysts for forming lower olefins via Fischer-Tropsch synthesis. Journal of Colloid and Interface Science, 516, 16-22. https://doi.org/10.1016/j.jcis.2018.01.017

Peralta, Y. M., Molina, R., Moreno, S. (2024). Chemical and structural properties of silica obtained from rice husk and its potential as a catalytic support. Journal of Environmental Chemichal Engineering, 12(2), 112370. https://doi.org/10.1016/j.jece.2024.112370

Peralta, Y. M., Molina, R., Moreno, S. (2025). Rice husk silica as a platform for iron biocatalysts via silanol group confinement. Water Process Engineering, 80, 109144. https://doi.org/10.1016/j.jwpe.2025.109144

Peralta, Y. M., Molina, R., Pérez, A., Moreno, S. (2025). Eco-innovation in action: Using rice husk-derived silica for highly dispersed iron catalysts in the oxidation of phenol. Bioresources Technology Reports, 31, 102202–102212. https://doi.org/10.1016/j.biteb.2025.102202

Peralta-Ladino, Y. M., Molina, R., Moreno, S. (2025). Novel synthesis of iron-based catalysts stabilized by oxygen defects on silica derived rice husk. Surfaces and Interfaces, 77, 108035. https://doi.org/10.1016/j.surfin.2025.108035

Rajesh, G., Bandyopadhyay, M., Das, D. (1999). Some studies on UASB bioreactors for the stabilization of low strength industrial effluents. Bioprocess Engineering, 21, 113-116. https://doi.org/10.1007/s004490050649

Ramprakash, B. & Muthukumar, K. (2014). Comparative study on the production of biohydrogen from rice mill wastewater. International Journal of Hydrogen Energy, 39(27), 14613-14621. https://doi.org/10.1016/j.ijhydene.2014.06.029

Sable, S. S., Shah, K. J., Chiang, P. C., Lo, S. L. (2018). Catalytic oxidative degradation of phenol using iron oxide promoted sulfonated-ZrO 2 by Advanced Oxidation Processes (AOPs). Journal of the Taiwan Institute of Chemical Engineers, 91, 434-440. https://doi.org/10.1016/j.jtice.2018.06.030

Singh, R. K. & Bajpai, S. (2025). Study of Biological Treatment of Rice Mill Wastewater Using Anaerobic Semicontinuous Reactors (ASCR). Nature Environment and Pollution Technology, 24(1), B4197. https://doi.org/10.46488/NEPT.2025.v24i01.B4197

Thommes, M., Kaneko, K., Neimark, A. V., Olivier, J. P., Rodriguez-Reinoso, F., Rouquerol, J., Sing, K. (2015). Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure and Applied Chemistry, 87(9-10), 1051-1069. https://doi.org/10.1515/pac-2014-1117

Vu, A. T., Xuan, T. N., & Lee, C. H. (2019). Preparation of mesoporous Fe2O3 ·SiO2 composite from rice husk as an efficient heterogeneous Fenton-like catalyst for degradation of organic dyes. Journal of Water Process Engineering, 28, 169-180. https://doi.org/10.1016/j.jwpe.2019.01.019

Wu, L., Ye, F., Lei, D., Miao, G., Liu, B., Li, Z., Xiao, J. (2018). Regeneration of AgXO@SBA-15 for reactive adsorptive desulfurization of fuel. Petroleum Science, 15(4), 857–869. https://doi.org/10.1007/s12182-018-0264-8

Zou, Y. & Yang, T. (2019). Chapter 9 - Rice Husk, Rice Husk Ash and Their Applications. In LZ. Cheong & X. Xu (Eds.), Rice Bran and Rice Bran Oil (pp. 207-246). Elsevier Inc.

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