CATALYTIC HYDROGENATION OF METHYL OLEATE BY RUTENIUM AND PALADIUM HOMOGENEOUS CATALYSTS
Vol. 34 No. 132 (2010), Chemical Sciences
Vol. 34 No. 132 (2010)

CATALYTIC HYDROGENATION OF METHYL OLEATE BY RUTENIUM AND PALADIUM HOMOGENEOUS CATALYSTS

Chemical Sciences
https://doi.org/10.18257/raccefyn.34(132).2010.2456
Published 2023-12-22
Andrés Sebastian Salinas Trujillo
Grupo de Catálisis, Departamento de Química, Universidad del Cauca, Calle 5 No. 4-70, Popayán, Colombia.
Fernando Cuenú Cabezas
Laboratorio de Síntesis Organometálica y Catálisis, Departamento de Química, Universidad del Quindío, Armenia, Colombia.
Maria Patricia Zuluaga Moreno
Grupo de Catálisis, Departamento de Química, Universidad del Cauca, Calle 5 No. 4-70, Popayán, Colombia.
Luis Alfonso Vargas Jiménez
Grupo de Catálisis, Departamento de Química, Universidad del Cauca, Calle 5 No. 4-70, Popayán, Colombia.
Alfonso Enrique Ramírez Sanabria
Grupo de Catálisis, Departamento de Química, Universidad del Cauca, Calle 5 No. 4-70, Popayán, Colombia.
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How to Cite

Salinas Trujillo, A. S., Cuenú Cabezas, F., Zuluaga Moreno, M. P., Vargas Jiménez, L. A., & Ramírez Sanabria, A. E. (2023). CATALYTIC HYDROGENATION OF METHYL OLEATE BY RUTENIUM AND PALADIUM HOMOGENEOUS CATALYSTS. Revista De La Academia Colombiana De Ciencias Exactas, Físicas Y Naturales, 34(132), 357–363. https://doi.org/10.18257/raccefyn.34(132).2010.2456
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Abstract

Methyl oleate hydrogenation with the homogeneous catalysts PdCl2(py)2, PdCl2(3-mpy)2, RuCl2(PPh3)2(2-acpy)2, RuCl2(PPh3)2(4-acpy)2, and RuCl2(PPh3)2(4-tbpy)2 was studied. The reaction was carried out at 100 °C, 30 bar of hydrogen pressure, and toluene as solvent. The substituent group and its position around the pyridine ring affect the catalysts' activity, suggesting that steric and electronic effects are involved in the reaction mechanism.

https://doi.org/10.18257/raccefyn.34(132).2010.2456

Keywords

methyl oleate | homogeneous hydrogenation | Palladium | Ruthenium complexes
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References

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