Resumen
Se estudió la oxidación de 2-mercaptoetanol y propanotiol con ftalocianinas de Co encapsuladas en zeolitas X e Y con diferente fuerza básica, generada por intercambio de cationes alcalinos. La oxidación se realizó en ausencia de NaOH y en condiciones de reacción similares al proceso MEROX industrial. Se estableció una correlación entre la actividad oxidativa y la fuerza básica del catalizador, se obtuvo una escala relativa de fuerza básica de los sólidos, como función del corrimiento de la banda de 407 nm del yodo. Se deduce que la fuerza básica del sólido es suficiente para promover la reacción de formación del disulfuro.
Palabras clave
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Agnes Z., Ferenc N. 2000. Rate Enhancement of Oxidation Reactions by the Encapsulation of Metal Phthalocyanine Complexes, Catal. Letter, 65: 135-139.
Albert B. R., Cheetham A. K., A. 2000. Synchrotron X-ray powder diffraction study of highly crystalline low-silica zeolite P during Na–Ca íon exchange, Microporous and Mesoporous Materials,34(2): 207-211.
Alcaraz J. J., Arena B. J., Gillespie R. D., Holmgren J. S. 1998. Solid base catalysts for mercaptan oxidation. Cat. Today, 43 (1-2): 89-99.
Balla RJ, Heicklen, J. 1985. Oxidation of sulfur compounds, 5. Rate coefficients for the CH3SH-NO2, reaction. J Phys Chem, 89: 4596-4600.
Barthomeuf D. 1984. Conjugate Acid-Base Pairs in Zeolites, J. Phys. Chem., 88(1): 42-45.
Basu B. V., Satapathy S., Bhatnagar A. K. 1993. Procesos merox y oxidación de metales relacionados, catalizados por ftalocianinas, Indian Oil Corporation, Limited Research and Development Center. Catal. Rev. Sci. Eng., 35 (4): 571-609.
Bricker J. C., Staehle B. E. 1987. US Patent 4705620
Chandrasekhar S., Pramada P. N. 2001. Sintering behavior of calcium exchanged low silica zeolites synthesized from kaolin, Ceramics International, 27(1): 105-114.
Chandrasekhar S., Pramada P. N. 2002. Thermal studies of low silica zeolites and their magnesium exchanged forms, Ceramics International, 28(2): 177-186.
Chatti I., Ghorbel A., Grange P., Colin J. M. 2002. Oxidation of mercaptans in light oil sweetening by cobalt(II) phthalocyaninehydrotalcite catalysts. Catal. Today, 75,113-117.
Choi S. Y., Park Y. S., Hong S. B., Yoon K. B. 1996. Iodine as a Visible Probe for the Evaluation of Zeolite Donor Strength, J. Am. Chem. Soc., 118 (39): 9377-9386.
Daohong X. Jialin Y. S. 1999. Study on the Oxidation Mechanism of Mixed Thiols in Light Oil Sweetening. 3. Apparent Kinetics of the Catalytic Cooxidation of Mixed Thiols in Gas-Liquid-Solid Systems. Ind. Eng. Chem. Res., 38: 1291-1294.
Daohong X. Jialin Y. S. , Su Y., Qiant J. 1995, Study on the Oxidation Mechanism of Mixed Thiols in Light Oil Sweetening. 1. Kinetics and Mechanism of Homogeneous Catalytic Cooxidation of Mixed 2-Methyl-2-propanethiol and Ethanethiol, Znd. Eng. Chem. Res., 34: 2001-2005.
Dyer A., Enamy H. 1985. The sodium-calcium exchange in zeolite A, Zeolites, 5(2): 66-67.
ILIEV. V. ILEVA A. BILYARSKA L. 1997. Oxidation and photooxidation of sulfur-containing compounds in the presence of immobilized phthalocyanine complexes, J. Mol. Catal. A: Chem. 126(2-3): 99-108.
JACOBS P. A., THIBAULT-STARZYK F., VAN PUYMBROECK M., PARTON R. Thiol-oxidation with zeolite encapsulated phthalocyanines: influence of the solid support. J. Mol Catal A: Chem. 109(1): 75-79
Kovacheva P., Arishtirova K. Davidova N. 1997.Effect of preparation of a CsX zeolite catalyst on the oxidative conversion of methane, Applied Catalysis A: General, 163(1-2): 255-260.
Kovacheva P., Arishtirova K. Davidova N. 1997. Characterization of lithium and cesium modified zeolite catalysts in the oxidative conversion of methane, Applied Catalysis A: General, 149(2): 277-287.
Lafoy C. J. 1985, US Patent 4562300.
Leung S. K. 1987. Cobalt phthalocyanine catalysed autooxidation of mercaptanos, Ph. D. Thesis, Calif Inst. Technol., Pasadena, Calif., U. S.
Liquornik M., Marcus Y. 1968. Íon exchange in molten salts. III. The íon-exchange properties of sodium zeolite A in molten sodium nitrate. The exchange with calcium and strontium cations, J. Phys. Chem. 72(13): 4704-4705.
Litter M. I. 1999. Heterogeneous photocatalysis: Transition metal ions in photocatalytic systems. Appl. Catal. B: Environ., 23(2-3): 89-114.
Mendoza O., Pedraza J., Martinez F., Páez-Mozo E. Photocatalytic oxidation of 2-mercaptoethanol by metal (II)-tetrasulfophthalocyanines intercalated in hydrotalcite; en proceso de publicación.
Morales L., Páez Mozo E. A. 1996. Síntesis de hidrotalcita utilizando tetrasulfoftalocianina metálica y su ensayo en la oxidación de mercaptoetanol. Actas del IV Simposio Colombiano de Catálisis, Bucaramanga (Colombia), 203-207.
Mortier W. J., Pluth, J. J. Smith J. V. 1975. Positions of catíons and molecules in zeolites with the mordenite-type framework I dehydrated Ca-exchanged ptilolite, Materials Research Bulletin, 10(10): 1037-1045.
Mortier W. J., Pluth, J. J. Smith J. V. . 1975. Positions of catíons and molecules in zeolites with the mordenite-type framework II dehydrated hydrogenptilolite, Materials Research Bulletin,10(12): 1319-1325.
Paez E., Gabriunas N., Luccaccione D. 1993. Cobalt Phthalocyanine Encapsulated in Y Zeolite: A Physochemical Study, J. Phys. Chem. 97(49): 12819-12827.
Paez E., Gabriunas N., Luccaccione D. , Jaramillo S., Martínez F., Pradilla J. 1994. Catalizadores complejos de Co encapsulados en zeolitas para oxidación de mercaptanos, XIV Simposio Iberoamericano de Catálisis, septiembre 12-16, Concepción, Chile, Actas, 585-590.
RAY S., VASUDEVAN, S. 2003. Encapsulation of cobalt phthalocyanine in zeolita Y: Evidence for nonplanar geometry, Inorganic Chem., 42: 1711-1719.
Ross R. A., Sood S. P. 1977. Catalytic Oxidation of Methyl Mercaptan over Cobalt Molybdate, Ind. Eng. Chem., Prod. Res. Dev., 16(2): 147-150.
Sherry H. S. 1966. Barium Íon Exchange of the Synthetic Zeolite Linde 4-A, J. Phys. Chem. 70(4): 1332-1334.
Tanabe K. 1985. Catálysis by Acids and Bases, Elseiver, Ámsterdam, 1.
Tanabe K. , Yamaguchi T. 1968. Solid Bases and their Catalytic Activity, J. Res. Inst. Catalysis, Hokkaido, Univ., 16(1): 425-447.
Tynjälä P., Pakkanen T. 1996. Acidic properties of ZSM-5 zeolite modified with Ba2+, Al3+ and La3+ íon-exchange, Journal of Molecular Catalysis A: Chemical, 110(2): 153-161.
Wallace T. J., Alanschriesheim H., Marvin B. 1964. Base-catalyzed oxidation of mercaptans in the presence of inorganic transition metal complexes, I & EC Process Designand Development, 3(3): 237-241.
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